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In contrast, at higher concentrations, MB may start to divert electrons away from the normal chain and inhibit the respiratory enzymes, which could decrease ATP generation and increase oxidative stress

de Gramont A, Van Cutsem E, Schmoll HJ, Tabernero J, Clarke S, Moore MJ, et al

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It may be pointed out here that earlier reports are available in literature which have demonstrated the enzyme-catalysed formation of dityrosine from tyrosine 7