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Breastfeeding Only 0.061.5% of maternal caffeine dose transfers through breastmilk, but newborns cannot metabolize it: caffeines half-life in newborns is up to 120 hours (five days) .[39][40] By 35 months, it decreases to ~14 hours

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[DOI] [PubMed] [Google Scholar] Reif A, Herterich S, Strobel A, Ehlis AC, Saur D, Jacob CP, Wienker T, Tpner T, Fritzen S, Walter U, Schmitt A, Fallgatter AJ, Lesch KP

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Participants were provided their assigned supplements and (b) studies repeated 2-weeks after starting supplements