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The solid according to claim 1, wherein the ligand L is a di-, tri- or tetracarboxylate ligand selected from the group consisting of: C 2 H 2 (CO 2 " ) 2 (fumarate), C 2 H 4 ( CO 2 " ) 2 (succinate), C 3 H 6 (CO 2 " ) 2 (glutarate), C 4 H 4 (CO 2 " ) 2 (muconate), C 4 H 8 (CO 2 " ) 2 (adipate) , C 7 H 14 (CO 2 " ) 2 (azelate), C 5 H 3 S (CO 2 " ) 2 (2,5-thiophene dicarboxylate), C 6 H 4 (CO 2 " ) 2 (terephthalate), C 6 H 2 N 2 (CCV) 2 (2,5-pyrazine dicarboxylate), C 10 H 6 (CO 2 " ) 2 (naphthalene-2,6-dicarboxylate), C 12 H 8 (CO 2 " ) 2 ( biphenyl-4,4'-dicarboxylate), C 12 H 8 N 2 (CO 2 " ) 2 6 H 3 ( CO 2 " ) 3 (benzne-1,2 ,4- tricarboxylate) , C 6 H 3 ( CO 2 " ) 3 ( benzne-1, 3,5- tricarboxylate) , C 24 H 15 ( CO 2 " ) 3 ( benzne-1, 3,5- tribenzoate) , C 6 H 2 ( CO 2 " ) 4 (benzne-1,2,4,5- ttracarboxylate, C 10 H 4 ( CO 2 " ) 4 ( naphtalne-2 , 3 , 6,7- ttracarboxylate) , C 10 H 4 (CO 2 " ) 4 (naphtalne-1, 4,5,8- ttracarboxylate), C 12 H 6 ( CO 2 " ) 4 (biphnyl-3,5,3 ' ,5' - ttracarboxylate) , et les analogues modifis choisis dans le groupe comprenant le 2-aminotrphtalate, le 2- nitrotrphtalate, le 2-mthyltrphtalate, le 2- chlorotrphtalate, le 2-bromotrphtalate, le 2,5- dihydroxotrphtalate , le ttrafluorotrphtalate, le le ttramthyltrphtalate, le dimthyl-4,4 ' - biphnydicarboxylate , le ttramthyl-4 , 4 ' - biphnydicarboxylate , le dicarboxy-4 , 4 ' - biphnydicarboxylate , le 2,5-pyrazyne dicarboxylate, le 2,5 diperfluoroterephthalate, azobenzene 4,4'- dicarboxylate, 3,3 ' -dichloro azobenzene 4,4'- dicarboxylate, 3 , 3 ' -dihydroxo azobenzene 4,4'- dicarboxylate, 3,3 '-diperfluoro azobenzene 4,4'- dicarboxylate, 3,5,3 ' ,5 '-azobenzene ttracarboxylate, 2,5-dimethyl terephthalate, perfluorosuccinate, perfluoromuconate, perfluoro glutarate, 3, 5, 3 ',5' perfluoro-4 , 4 ' -azobenzene dicarboxylate , 3,3'- diperfluoro azobenzene 4,4 '-dicarboxylate.(azobenzenedicarboxylate), C 6 H 3 (CO 2 - ) 3 (benzene-1,2,4-tricarboxylate), C 6 H 3 (CO 2 - ) 3 (benzene-1,3,5-tricarboxylate), C 24 H 15 (CO 2 " ) 3 (benzene-1,3,5-tribenzoate), C 6 H 2 (CO 2 " ) 4 (benzene-1,2,4,5-tetracarboxylate, C 10 H 4 (CO 2 ") 4 (naphthalene-2, 3, 6,7-tetracarboxylate), C 10 H 4 (CO 2") 4 (naphthalene-1, 4,5,8- tetracarboxylate), C 12 H 6 (CO 2 ") 4 (biphenyl-3,5,3 ', 5'-tetracarboxylate), and modified analogs selected from the group consisting of 2-aminoterephthalate, 2-nitroterephthalate, 2-methylterephthalate, 2-chloroterephthalate, 2-bromoterephthalate , 2,5-dihydroxterephthalate, tetrafluoroterephthalate, tetramethylterephthalate, dimethyl-4,4'-biphenydicarboxylate, tetramethyl-4,4'-biphenydicarboxylate, dicarboxy-4,4'-biphenydicarboxylate, 2,5-dihydroxterephthalate, pyrazyne dicarboxylate, 2,5 diperfluoroterephthalate, azobenzene 4,4'-dicarboxylate, 3,3 dichloroazobenzene 4,4'-dicarboxylate, 3,3'-dihydroxoazobenzene 4,4'-dicarboxylate, 3,3'-diperfluoroazobenzene 4,4'-dicarboxylate, 3,5,3 ', 5'-azobenzene tetracarboxylate, 2,5-dimethyl terephthalate, perfluorosuccinate, perfluoromuconate, perfluoro glutarate, 3,5 ', 3', 5 'perfluoro-4,4'-azobenzene dicarboxylate, 3,3'-diperfluoro azobenzene 4,4'-dicarboxylate

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For instance, Shaman Smokes indicate they are hemp cigarettes containing significant levels of CBD and other cannabinoids like CBG and CBC

Finally, to establish the effect of water on volatiles profile, a representative product (mango-flavored hookah tobacco) was analyzed in the presence of water at 190 C and results of attained volatiles were compared to previous dry analysis (Supplementary Fig